2. Academic Validation
  3. Triterpenoid glycosides from Ladenbergia hexandra Klotzsch

Triterpenoid glycosides from Ladenbergia hexandra Klotzsch

  • Phytochemistry. 2017 Apr;136:147-155. doi: 10.1016/j.phytochem.2017.01.014.
Megumi Furukawa 1,  Satoshi Kamo 1,  Mitsuko Makino 1,  Masahiro Kurita 1,  Keiichi Tabata 1,  Keiichi Matsuzaki 1,  Takashi Suzuki 1,  Taketo Uchiyama 2
Affiliations

Affiliations

  • 1 School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi, Chiba 274-8555, Japan.
  • 2 School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi, Chiba 274-8555, Japan. Electronic address: [email protected].
PMID: 28153444 DOI: 10.1016/j.phytochem.2017.01.014
Abstract

From the bark of Ladenbergia hexandra Klotzsch, ten triterpenoid glycosides were isolated along with five known compounds, and their structures were determined based on extensive NMR and mass spectroscopic, GC and HPLC analyses. Some triterpenoid glycosides contained 6-deoxy-D-allose or D-allose as a sugar moiety. The absolute stereochemical assignment of the sugars was determined by comparison with synthetic samples, as well as by GC and HPLC analysis.

Keywords

6-Deoxy-β-D-allose; Glycosyl iodide; Ladenbergia hexandra; Rubiaceae; Triterpene glycoside; β-D-allose; β-D-quinovose.

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