2. Academic Validation
  3. Induced Circular Dichroism of Jet-Cooled Phenol Complexes with ( R)-(-)-2-Butanol

Induced Circular Dichroism of Jet-Cooled Phenol Complexes with ( R)-(-)-2-Butanol

  • J Phys Chem A. 2019 Oct 17;123(41):8913-8920. doi: 10.1021/acs.jpca.9b07237.
Aram Hong 1,  Ahreum Min 1,  Heeseon Jang 1,  Cheol Joo Moon 2,  Changseop Jeong 1,  Myong Yong Choi 2,  Jiyoung Heo 3,  Nam Joon Kim 1
Affiliations

Affiliations

  • 1 Department of Chemistry , Chungbuk National University , Cheongju , Chungbuk 28644 , Korea.
  • 2 Department of Chemistry (BK21+) and Research Institute of Natural Science , Gyeongsang National University , Jinju 52828 , Korea.
  • 3 Department of Green Chemical Engineering , Sangmyung University , Cheonan , Chungnam 31066 , Korea.
PMID: 31549840 DOI: 10.1021/acs.jpca.9b07237
Abstract

The induced circular dichroism (ICD) of phenol complexed with (R)-(-)-2-butanol [PhOH-(-)BOH] in a supersonic jet is investigated using resonant two-photon ionization circular dichroism (R2PICD) spectroscopy. The R2PICD spectrum of PhOH-(-)BOH exhibits nonzero ICD bands near the absorption region of bare PhOH, where (-)BOH is transparent. Two different conformers containing a single hydrogen bond between PhOH and (-)BOH are identified using ultraviolet-ultraviolet hole-burning and infrared ion-dip spectroscopy combined with quantum theoretical calculations. The ICD values of the two conformers are similar to each other. To understand these similar ICD effects of the conformers, the geometrical asymmetry of the PhOH moiety bound to (-)BOH and the coupling strength of the electric transition dipole moments between PhOH and (-)BOH are estimated. Comparing the ICD values of PhOH-(-)BOH with those of PhOH-(-)-l-methyl lactate in the previous report [ Hong , A. ; J. Phys. Chem. Lett. 2018 , 9 , 476 -480 ], we investigate the physical properties that may govern the differences of the ICD values between the two complexes.

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