[IrCl(COE)2]2  (Synonyms: Chlorobis(cyclooctene)iridium(I)dimer)

[IrCl(COE)2]2 (Chlorobis(cyclooctene)iridium(I)dimer) is a transition metal catalyst with remarkable catalytic activity. It is widely used in catalyzing a variety of organic reactions, especially in the synthesis of unsaturated compounds. In addition, [IrCl(COE)2]2 has shown potential anti-tumor properties in biochemical research.

896.13

C₃₂H₅₆Cl₂Ir₂

12246-51-4

Solid

[CH]1(CCCCCC2)=[CH]2[Ir+]134([CH]5=[CH]4CCCCCC5)[Cl-][Ir+]67([CH]8=[CH]6CCCCCC8)([CH]9=[CH]7CCCCCC9)[Cl-]3

Room temperature in continental US; may vary elsewhere.

4°C, protect from light, stored under nitrogen

*In solvent : -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen)

• [1]. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity

  [2]. Transition-metal-catalyzed immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions

  [3]. Iridium (I)-catalyzed hydrogen peroxide oxidation of hydroxamic acids and hetero DielsAlder reaction of the acyl nitroso intermediates with cyclopentadiene

  [4]. Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex

  [5]. An efficient and recyclable catalytic system comprising nano-iridium (0) and a pyridinium salt of nido-carboranyldiphosphine for the synthesis of one-dimensional boronate esters via hydroboration reaction

  [6]. Allylic amination by a DNAdieneiridium (I) hybrid catalyst

  [7]. Versatile Pd (II)-Catalyzed C H Activation/Aryl Aryl Coupling of Benzoic and Phenyl Acetic Acids