76189-56-5
76189-56-5
Chemical Structure
(S)-BINAP
- CAS No.: 76189-56-5
- Formula:C44H32P2
- Molecular Weight:622.67
IUPAC Name: (S)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthalene
InChIKey: MUALRAIOVNYAIW-UHFFFAOYSA-N
SMILES: C1(C=CC=C2)=C2[C@@]([C@@]3=C(C=CC=C4)C4=CC=C3P(C5=CC=CC=C5)C6=CC=CC=C6)=C(P(C7=CC=CC=C7)C8=CC=CC=C8)C=C1
Biological Activity: (S)-BINAP is the S-isomer of BINAP (HY-Y0003). BINAP is a chiral bisphosphine ligand. (S)-BINAP can be used to assist in the synthesis of compounds with anticancer activity[1][2][3].
| Cat. No. | Product Name | Purity | Description | Pricing | |||||||||||||||||||
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(S)-BINAP | 99.71% | (S)-BINAP is the S-isomer of BINAP (HY-Y0003). BINAP is a chiral bisphosphine ligand. (S)-BINAP can be used to assist in the synthesis of compounds with anticancer activity. | ||||||||||||||||||||
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References
- [1]. Tunik S P, et al. Reaction of (S)-BINAP with H4Ru4 (CO) 12. The First Example of Face-Bridging BINAP Coordination and 100% Stereoselectivity in Formation of a Chiral Tetranuclear Cluster Framework. Organometallics, 2004, 23(3): 568-579.
- [2]. Li M, et al. Stereoselective Total Synthesis of Formosanol, Tsugacetal, and Methyl β-Conidendral. Org Lett. 2022 Oct 28;24(42):7812-7816. [Content Brief]
- [3]. Xin Jin, et al. Synthesis and characterization of a high-purity chiral 5,5'-disulfonato-BINAP ligand and its application in asymmetric hydrogenation of β-keto esters. Molecular Catalysis, 2021, 507, 111562.
Keywords
