3,5-Dihydroxybiphenyl synthase

3,5-Dihydroxybiphenyl synthase (EC 2.3.1.177) is a polyketide synthase that is involved in the production of the phytoalexin aucuparin. 2-Hydroxybenzoyl-CoA can also act as substrate but it leads to the derailment product 4-hydroxycoumarin (cf.

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