27126-76-7
![[Hydroxy(tosyloxy)iodo]benzene Chemical Structure](http://file.medchemexpress.cn/product_pic/hy-34619.gif "[Hydroxy(tosyloxy)iodo]benzene Chemical Structure")
Chemical Structure
[Hydroxy(tosyloxy)iodo]benzene
- CAS No.: 27126-76-7
- Formula:C13H13IO4S
- Molecular Weight:392.21
IUPAC Name: hydroxy(phenyl)-l3-iodanyl 4-methylbenzenesulfonate
InChIKey: LRIUKPUCKCECPT-UHFFFAOYSA-N
SMILES: OI(C1=CC=CC=C1)OS(C2=CC=C(C)C=C2)(=O)=O
Biological Activity: [Hydroxy(tosyloxy)iodo]benzene is a versatile reagent for the mild oxidation of aryl iodides at the iodine atom by ligand transfer. [Hydroxy(tosyloxy)iodo]benzene is an effective reagent for the one-step conversion of ketones to the corresponding α-tosyloxy ketones. [Hydroxy(tosyloxy)iodo]benzene is also a Bronsted acid and is expected to catalyze the enolization of ketones[1][2].
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[Hydroxy(tosyloxy)iodo]benzene | 99.1% | [Hydroxy(tosyloxy)iodo]benzene is a versatile reagent for the mild oxidation of aryl iodides at the iodine atom by ligand transfer. [Hydroxy(tosyloxy)iodo]benzene is an effective reagent for the one-step conversion of ketones to the corresponding α-tosyloxy ketones. [Hydroxy(tosyloxy)iodo]benzene is also a Bronsted acid and is expected to catalyze the enolization of ketones. | ||||||||||||||||||||
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- [1]. Gerald F. Koser, et al., [Hydroxy(tosyloxy)iodo]benzene, a Versatile Reagent for the Mild Oxidation of Aryl Iodides at the Iodine Atom by Ligand Transfer. J. Org. Chem. 1980, 45, 1542-1543.
- [2]. Gerald F. Koser, et al., One-Step -Tosyloxylation of Ketones with [Hydroxy(tosyloxy)iodo]benzene. J. Org. Chem. 1982, 47, 2487-2489.
Keywords
