27126-76-7

[Hydroxy(tosyloxy)iodo]benzene Chemical Structure
27126-76-7

Chemical Structure

[Hydroxy(tosyloxy)iodo]benzene

  • CAS No.: 27126-76-7
  • Formula:C13H13IO4S
  • Molecular Weight:392.21

IUPAC Name: hydroxy(phenyl)-l3-iodanyl 4-methylbenzenesulfonate

InChIKey: LRIUKPUCKCECPT-UHFFFAOYSA-N

SMILES: OI(C1=CC=CC=C1)OS(C2=CC=C(C)C=C2)(=O)=O

Biological Activity: [Hydroxy(tosyloxy)iodo]benzene is a versatile reagent for the mild oxidation of aryl iodides at the iodine atom by ligand transfer. [Hydroxy(tosyloxy)iodo]benzene is an effective reagent for the one-step conversion of ketones to the corresponding α-tosyloxy ketones. [Hydroxy(tosyloxy)iodo]benzene is also a Bronsted acid and is expected to catalyze the enolization of ketones[1][2].

Cat. No. Product Name Purity Description Pricing
HY-34619 		[Hydroxy(tosyloxy)iodo]benzene 99.1% [Hydroxy(tosyloxy)iodo]benzene is a versatile reagent for the mild oxidation of aryl iodides at the iodine atom by ligand transfer. [Hydroxy(tosyloxy)iodo]benzene is an effective reagent for the one-step conversion of ketones to the corresponding α-tosyloxy ketones. [Hydroxy(tosyloxy)iodo]benzene is also a Bronsted acid and is expected to catalyze the enolization of ketones.
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This compound is listed in the SVHC (Substances of Very High Concern) candidate list of ECHA (European Chemicals Agency).

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Structural Analogs

References

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