36431-52-4
Chemical Structure
LL-Z1220
- CAS No.: 36431-52-4
- Formula:C11H8O4
- Molecular Weight:204.18
IUPAC Name: 2-((1R,2R,4R,7R)-3,8-dioxatricyclo[5.1.0.02,4]oct-5-en-5-yl)-4H-pyran-4-one
InChIKey: WWHMQTDCCWMKQY-GWOFURMSSA-N
SMILES: O=C1C=C(OC=C1)C2=C[C@]3(O[C@]3([C@@]4(O[C@]24[H])[H])[H])[H]
Biological Activity: LL-Z1220 is a novel antibiotic with the structure of 2-(3,8-dioxopentacyclo[5.1.0.0^~^~]oct-5-en-5-yl)-4H-pyran-4-one. This appears to be the first reported natural product containing a benzene dioxide group. This antibiotic readily undergoes valence isomerization to form 1,4-dioxopentacyclo. The chemical and spectroscopic properties of the antibiotic suggest that the benzene dioxide has a cis configuration.
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LL-Z1220 | LL-Z1220 is a novel antibiotic with the structure of 2-(3,8-dioxopentacyclo[5.1.0.0^~^~]oct-5-en-5-yl)-4H-pyran-4-one. This appears to be the first reported natural product containing a benzene dioxide group. This antibiotic readily undergoes valence isomerization to form 1,4-dioxopentacyclo. The chemical and spectroscopic properties of the antibiotic suggest that the benzene dioxide has a cis configuration. | |||||||||||||||||||||
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Keywords
