192139-92-7
![RuCl(p-cymene)[(R,R)-Ts-DPEN] Chemical Structure](http://file.medchemexpress.cn/product_pic/hy-w001069.gif "RuCl(p-cymene)[(R,R)-Ts-DPEN] Chemical Structure")
Chemical Structure
RuCl(p-cymene)[(R,R)-Ts-DPEN]
Synonym(s): RuCl[(R,R)-Tsdpen](p-cymene)
- CAS No.: 192139-92-7
- Formula:C31H35ClN2O2RuS
- Molecular Weight:636.21
InChIKey: AZFNGPAYDKGCRB-AGEKDOICSA-M
SMILES: Cc1ccc(C(C)C)cc1.Cl[Ru]([NH2]2)N([C@H](C3=CC=CC=C3)[C@H]2C4=CC=CC=C4)S(C5=CC=C(C)C=C5)(=O)=O
Biological Activity: RuCl (p-cymene)[(R,R)-Ts-DPEN] (RuCl[(R,R)-Tsdpen](p-cymene)) is a Noyori-type chiral ruthenium asymmetric transfer hydrogenation catalyst. RuCl (p-cymene)[(R,R)-Ts-DPEN] is widely used in the asymmetric transfer hydrogenation and enantioselective reduction of ketones, imines and quinolines to construct specific stereoisomers with high optical purity[1][2].
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RuCl(p-cymene)[(R,R)-Ts-DPEN] | RuCl (p-cymene)[(R,R)-Ts-DPEN] (RuCl[(R,R)-Tsdpen](p-cymene)) is a Noyori-type chiral ruthenium asymmetric transfer hydrogenation catalyst. RuCl (p-cymene)[(R,R)-Ts-DPEN] is widely used in the asymmetric transfer hydrogenation and enantioselective reduction of ketones, imines and quinolines to construct specific stereoisomers with high optical purity. | |||||||||||||||||||||
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[1]. Delcourt, M. L., et al. (2018). Highly enantioselective desymmetrization of centrosymmetric pseudo-para-diformyl [2.2] paracyclophane via asymmetric transfer hydrogenation. ACS Catalysis, 8(7), 6612-6616.
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[2]. Bartlett SL, Johnson JS. Synthesis of Complex Glycolates by Enantioconvergent Addition Reactions. Acc Chem Res. 2017 Sep 19;50(9):2284-2296.
[Content Brief]
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