RuCl(p-cymene)[(R,R)-Ts-DPEN]
Based on 1 Customer Validation
RuCl (p-cymene)[(R,R)-Ts-DPEN] (RuCl[(R,R)-Tsdpen](p-cymene)) is a Noyori-type chiral ruthenium asymmetric transfer hydrogenation catalyst. RuCl (p-cymene)[(R,R)-Ts-DPEN] is widely used in the asymmetric transfer hydrogenation and enantioselective reduction of ketones, imines and quinolines to construct specific stereoisomers with high optical purity.
For research use only. We do not sell to patients.
- CAS No.: 192139-92-7
- Formula: C31H35ClN2O2RuS
- Molecular Weight:636.21
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Storage:
-20°C, stored under nitrogen
* In solvent : -80°C, 6 months; -20°C, 1 month (stored under nitrogen)
![RuCl(p-cymene)[(R,R)-Ts-DPEN] Chemical Structure](https://file.medchemexpress.com/product_pic/hy-w001069.gif "Click to View RuCl(p-cymene)[(R,R)-Ts-DPEN] Chemical Structure")
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Biological Activity
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Chemical Information
- Purity & Documentation
- References
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Help & FAQs
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HY-Y1109
Dichloro(p-cymene)ruthenium(II) dimer
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HY-79986
Diiodo(p-cymene)ruthenium(II) dimer
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![[Rh(cod)Cl]2](https://file.medchemexpress.com/product_pic/hy-y1094.gif)
HY-Y1094
[Rh(cod)Cl]2
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HY-W033466
Dichloro(benzene)ruthenium(II) dimer
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HY-W002502
(DHQ)2PHAL
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HY-W035145
Tris2,2′-bipyridineruthenium(II) hexafluorophosphate
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HY-W020952
Palladium(Ⅱ) acetylacetonate
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HY-W096169D
Platinum
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HY-W007596
Tris(2-phenylpyridinato-C2,N)iridium(III)
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HY-W048457
Palladium hydroxide on activated carbon(20%)(wetted with ca. 55% Water)
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![Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct](https://file.medchemexpress.com/product_pic/hy-21623.gif)
HY-21623
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct
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![[Ir(ppy)2(bpy)]PF6](https://file.medchemexpress.com/product_pic/hy-w072530.gif)
HY-W072530
[Ir(ppy)2(bpy)]PF6
Biological Activity
RuCl(p-cymene)[(R,R)-Ts-DPEN] catalyzes asymmetric transfer hydrogenation of α-aryl-α,γ-dioxo-butyric acid esters, selectively reducing only the α-carbonyl group to form chiral α-hydroxy-γ-keto-butyric acid ethyl esters with ligand-matching (R,R) configuration, key building blocks for bioactive compounds including Croomycin, Citrafungins, and other natural extracts[2].
MedChemExpress (MCE) has not independently confirmed the accuracy of these methods. They are for reference only.
Chemical Information
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CAS No. 192139-92-7
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Appearance Solid
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Molecular Weight 636.21
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Formula C31H35ClN2O2RuS
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Color Yellow to brown
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SMILES
Cc1ccc(C(C)C)cc1.Cl[Ru]([NH2]2)N([C@H](C3=CC=CC=C3)[C@H]2C4=CC=CC=C4)S(C5=CC=C(C)C=C5)(=O)=O
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Synonyms
RuCl[(R,R)-Tsdpen](p-cymene)
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Shipping
Room temperature in continental US; may vary elsewhere.
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Storage
-20°C, stored under nitrogen
* In solvent : -80°C, 6 months; -20°C, 1 month (stored under nitrogen)
Purity & Documentation
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Data Sheet (287 KB)
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SDS (393 KB)
- English - EN (393 KB)
- Français - FR (393 KB)
- Deutsch - DE (393 KB)
- Norwegian - NO (393 KB)
- Español - ES (393 KB)
- Swedish - SV (393 KB)
- Italian - IT (393 KB)
- Korean - KR (393 KB)
- Portuguese - PT (393 KB)
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Handling Instructions (2659 KB)
References
Calculators
Concentration (start) × Volume (start) = Concentration (final) × Volume (final)
RuCl(p-cymene)[(R,R)-Ts-DPEN] Related Classifications
HY-W001069 Related Classifications
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- RuCl(p-cymene)[(R,R)-Ts-DPEN]
- 192139-92-7
- RuCl[(R,R)-Tsdpen](p-cymene)
- Biochemical Assay Reagents
- DMF
- asymmetric transfer hydrogenation
- 4-hydroxymethyl-16-isopropoxycarbonyl[2.2]paracyclophane
- HCOOH/Et3N
- pseudo-gem diformyl[2.2]paracyclophane
- chiral α-hydroxy-γ-keto-butyric acid ethyl esters
- centrosymmetric pseudo-para-diformyl[2.2]paracyclophane
- Croomycin
- 4-formyl-16-hydroxymethyl[2.2]paracyclophane
- α-aryl-α,γ-dioxo-butyric acid esters
- Inhibitor
- inhibitor
- inhibit