New sesquiterpenoid glycoside and phenylpropanoid glycosides from the tuber of Ophiopogon japonicus

  • J Asian Nat Prod Res. 2016 Jun;18(6):520-7. doi: 10.1080/10286020.2015.1121996.
Shi-Qiao Liu  1  2 Li-Ping Kang  2 Jie Zhang  3 Yi-Xun Liu  2 Yang Zhao  2 Bin Liu  1 Bai-Ping Ma  2
Affiliations
  • 1. a School of Chinese Materia Medica , Beijing University of Chinese Medicine , Beijing 100102 , China.
  • 2. b Beijing Institute of Radiation Medicine , Beijing 100850 , China.
  • 3. c Ovation Health Science and Technology Co. Ltd. , Langfang 065001 , China.
Abstract

A new sesquiterpenoid glycoside, cryptomeridiol 11-O-β-d-xylopyranosyl-(1→6)-β-d- glucopyranoside (1), two new phenylpropanoid Glycosides, 3,4-dihydroxy-allylbenzene 3-O-β-d-glucopyranosyl-4-O-β-d-apiofuranosyl-(1→6)-β-d-glucopyranoside (2), and 3,4,5-trihydroxy-allylbenzene 3-O-β-d-glucopyranosyl-4-O-β-d-glucopyranoside (3), along with four known phenylpropanoid Glycosides (4-7), were isolated from the tuber of Ophiopogon japonicus. Compounds 4-7 were obtained from the genus Ophiopogon for the first time. Their structures were elucidated by spectroscopic methods, including 1D and 2D NMR and HR-ESI-MS.

Keywords
Ophiopogon japonicus; phenylpropanoid glycoside; sesquiterpenoid glycoside.
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