149560-97-4
149560-97-4
Chemical Structure
Spinosyn A aglycone
Synonym(s): (-)-Spinosyn A aglycon
- CAS No.: 149560-97-4
- Formula:C24H34O5
- Molecular Weight:402.52
InChIKey: DIHUILSVOGYVDG-MRAVEKNJSA-N
SMILES: O[C@H]1C[C@@]2([H])[C@@]3([H])[C@](C=C[C@]2([H])C1)([H])[C@@]4([H])C(C([C@@H]([C@H](CCC[C@@H](OC(C4)=O)CC)O)C)=O)=C3
Biological Activity: Spinosyn A aglycone ((-)-Spinosyn A aglycon) is an aglycone form of the insecticide Spinosyn A (HY-B0767). Spinosyn A aglycone is an acid degradation product produced by hydrolysis of both saccharide groups on spinosyn A[1][2].
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Spinosyn A aglycone | Spinosyn A aglycone ((-)-Spinosyn A aglycon) is an aglycone form of the insecticide Spinosyn A (HY-B0767). Spinosyn A aglycone is an acid degradation product produced by hydrolysis of both saccharide groups on spinosyn A. | |||||||||||||||||||||
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References
- [1]. Winbush SM, et al. Total synthesis of (-)-spinosyn A: examination of structural features that govern the stereoselectivity of the key transannular Diels-Alder reaction. J Org Chem. 2008 Mar 7;73(5):1818-29. [Content Brief]
- [2]. Creemer LC, et al. Conversion of spinosyn A and spinosyn D to their respective 9- and 17-pseudoaglycones and their aglycones. J Antibiot (Tokyo). 1998 Aug;51(8):795-800. [Content Brief]
Keywords
