Synthesis and biological evaluation of quinoline derivatives as potential anti-prostate cancer agents and Pim-1 kinase inhibitors

  • Bioorg Med Chem. 2016 Apr 15;24(8):1889-97. doi: 10.1016/j.bmc.2016.03.016.
Kun Li  1 Ying Li  2 Di Zhou  1 Yinbo Fan  1 Hongye Guo  1 Tianyi Ma  1 Jiachen Wen  1 Dan Liu  3 Linxiang Zhao  4
Affiliations
  • 1. Key Laboratory of Structure-Based Drugs Design & Discovery of Ministry of Education, Shenyang Pharmaceutical University, Shenyang 110016, China.
  • 2. School of Life Sciences and Biopharmaceutics, Shenyang Pharmaceutical University, Shenyang 110016, China.
  • 3. Key Laboratory of Structure-Based Drugs Design & Discovery of Ministry of Education, Shenyang Pharmaceutical University, Shenyang 110016, China. Electronic address: [email protected].
  • 4. Key Laboratory of Structure-Based Drugs Design & Discovery of Ministry of Education, Shenyang Pharmaceutical University, Shenyang 110016, China. Electronic address: [email protected].
Abstract

In this work, a series of quinoline derivatives were designed and synthesized as antitumor agents. Most quinolines showed potent anti-proliferative activity against human prostatic Cancer PC-3 cell line. Among which, 9d, 9f and 9g were the most effective compounds with GI50 values of 2.60, 2.81 and 1.29 μM, respectively. Structure-activity relationship analysis indicated that the secondary amine linked quinoline and pyridine ring played an important role in the anti-proliferative effects. Mechanistic studies revealed that 9g was a potential Pim-1 kinase inhibitor with abilities of cell cycle arrest and Apoptosis induction. Considering of the increased activity of Pim-1 in prostate Cancer, such compounds have potential to be developed as anti-prostate Cancer agents.

Keywords
Anti-proliferative activity; Pim-1 kinase inhibitor; Prostate cancer; Quinoline derivatives.