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  3. Trifluoromethanesulfonate lithium

Trifluoromethanesulfonate lithium  (Synonyms: Triflate lithium; Trifluoromethylsulfonate lithium; Trifluoromethanesulphonic acid lithium)

Cat. No.: HY-21170B Purity: 99.9%
Handling Instructions Technical Support

Trifluoromethanesulfonate (Triflate;Trifluoromethylsulfonate) lithium is a stable lithium salt and dopant with four resonance states, which is commonly used as an electrolyte component in polymer light-emitting electrochemical cells and primary lithium batteries. Trifluoromethanesulfonate lithiumalso acts as a catalyst for the preparation of the herbicide Imazapyr. In MEH-PPV-based light-emitting electrochemical cells, Trifluoromethanesulfonate lithium promotes electrochemical p-type doping at the anode interface under applied bias, thereby facilitating the formation of p-i-n junctions, exciton generation, and light emission. Trifluoromethanesulfonate lithiumexhibits strong ion pairing in non-aqueous electrolytes, but its electrochemical stability window is narrower than that of lithium bistrifluoromethylsulfonyl imidee.

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Trifluoromethanesulfonate lithium

Trifluoromethanesulfonate lithium Chemical Structure

CAS No. : 33454-82-9

Size Price Stock Quantity
Solid + Solvent (Highly Recommended)
10 mM * 1 mL in DMSO
ready for reconstitution
In-stock
Solution
10 mM * 1 mL in DMSO In-stock
Solid
25 g In-stock
50 g   Get quote  

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Customer Review

Based on 1 publication(s) in Google Scholar

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Description

Trifluoromethanesulfonate (Triflate;Trifluoromethylsulfonate) lithium is a stable lithium salt and dopant with four resonance states, which is commonly used as an electrolyte component in polymer light-emitting electrochemical cells and primary lithium batteries. Trifluoromethanesulfonate lithiumalso acts as a catalyst for the preparation of the herbicide Imazapyr. In MEH-PPV-based light-emitting electrochemical cells, Trifluoromethanesulfonate lithium promotes electrochemical p-type doping at the anode interface under applied bias, thereby facilitating the formation of p-i-n junctions, exciton generation, and light emission. Trifluoromethanesulfonate lithiumexhibits strong ion pairing in non-aqueous electrolytes, but its electrochemical stability window is narrower than that of lithium bistrifluoromethylsulfonyl imidee[1][2][3].

In Vitro

Lithium trifluoromethanesulfonate is used in MEH-PPV:PEO:LiCF3SO3 blend films prepared by spin-coating. Compared with pure MEH-PPV films, the intrachain exciton emission peak of MEH-PPV in the films with a PEO/Li+ ratio ~30 shows a red shift of approximately 10 nm, which may indicate a transition of molecular chains from a curled and disordered state to a more extended, ordered state with better electron delocalization[1].

MedChemExpress (MCE) has not independently confirmed the accuracy of these methods. They are for reference only.

Molecular Weight

156.01

Formula

CF3SO3Li

CAS No.
Appearance

Solid

Color

White to off-white

SMILES

O=S(C(F)(F)F)(O[Li])=O

Shipping

Room temperature in continental US; may vary elsewhere.

Storage

4°C, sealed storage, away from moisture

*In solvent : -80°C, 6 months; -20°C, 1 month (sealed storage, away from moisture)

Solvent & Solubility
In Vitro: 

DMSO : 100 mg/mL (640.98 mM; Need ultrasonic; Hygroscopic DMSO has a significant impact on the solubility of product, please use newly opened DMSO)

Preparing
Stock Solutions
Concentration Solvent Mass 1 mg 5 mg 10 mg
1 mM 6.4098 mL 32.0492 mL 64.0985 mL
5 mM 1.2820 mL 6.4098 mL 12.8197 mL
View the Complete Stock Solution Preparation Table

* Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (sealed storage, away from moisture). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.

  • Molarity Calculator

  • Dilution Calculator

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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Volume
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Molecular Weight *

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

Concentration (start)

C1

×
Volume (start)

V1

=
Concentration (final)

C2

×
Volume (final)

V2

In Vivo Dissolution Calculator
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Recommended: Prepare an additional quantity of animals to account for potential losses during experiments.
Calculation results:
Working solution concentration: mg/mL
Purity & Documentation

Purity: 99.9%

References

Complete Stock Solution Preparation Table

* Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (sealed storage, away from moisture). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.

Optional Solvent Concentration Solvent Mass 1 mg 5 mg 10 mg 25 mg
DMSO 1 mM 6.4098 mL 32.0492 mL 64.0985 mL 160.2461 mL
5 mM 1.2820 mL 6.4098 mL 12.8197 mL 32.0492 mL
10 mM 0.6410 mL 3.2049 mL 6.4098 mL 16.0246 mL
15 mM 0.4273 mL 2.1366 mL 4.2732 mL 10.6831 mL
20 mM 0.3205 mL 1.6025 mL 3.2049 mL 8.0123 mL
25 mM 0.2564 mL 1.2820 mL 2.5639 mL 6.4098 mL
30 mM 0.2137 mL 1.0683 mL 2.1366 mL 5.3415 mL
40 mM 0.1602 mL 0.8012 mL 1.6025 mL 4.0062 mL
50 mM 0.1282 mL 0.6410 mL 1.2820 mL 3.2049 mL
60 mM 0.1068 mL 0.5342 mL 1.0683 mL 2.6708 mL
80 mM 0.0801 mL 0.4006 mL 0.8012 mL 2.0031 mL
100 mM 0.0641 mL 0.3205 mL 0.6410 mL 1.6025 mL
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Product Name:
Trifluoromethanesulfonate lithium
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HY-21170B
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