Ir[p-F(Me)ppy]2(dtbbpy)PF6 

Ir[p-F (Me) ppy]₂ (dtbbpy) PF₆ is a cyclometalated iridium (III) complex. Ir[p-F (Me) ppy]₂ (dtbbpy) PF₆ absorbs visible light (460 nm) to form a long-lived charge-separated excited state. Ir[p-F (Me) ppy]₂ (dtbbpy) PF₆ is applicable to visible light-mediated photocatalytic organic transformation reactions^[1].

Ir[p-F (Me) ppy]₂ (dtbbpy) PF₆ is a highly efficient photosensitizer with strong visible light absorption capacity, long-lived excited state, and excellent quenching kinetic properties, and it adopts reductive quenching as the dominant mechanism in hydrogen production systems^[1].
Ir[p-F (Me) ppy]₂ (dtbbpy) PF₆ possesses redox properties and can provide high-energy reducing equivalents via a reductive quenching process, thereby enabling the efficient reduction of rhodium (III) hydrogen evolution catalysts in hydrogen production systems^[1].

MedChemExpress (MCE) has not independently confirmed the accuracy of these methods. They are for reference only.

977.99

C₄₂H₄₂F₈IrN₄P^-

808142-88-3

Solid

F[P-](F)(F)(F)(F)F.CC1=CC=C(C2=C([Ir]34(C5=C(C6=[N]4C=C(C)C=C6)C=CC(F)=C5)7[N](C=CC(C(C)(C)C)=C8)=C8C9=CC(C(C)(C)C)=CC=[N]93)C=C(F)C=C2)[N]7=C1

Room temperature in continental US; may vary elsewhere.

4°C, protect from light, stored under nitrogen

*In solvent : -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen)

• [1]. Cline ED, et al. Homogeneous catalytic system for photoinduced hydrogen production utilizing iridium and rhodium complexes. Inorg Chem. 2008;47(22):10378-10388.  [Content Brief]