[Ir(dF(Me)ppy)2(dtbbpy)]PF6
Based on 1 Customer Validation
[Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a blue-green luminescent material. [Ir(dF(Me)ppy)2(dtbbpy)]PF6 exhibits irregular emission, with its emission peak maxima located at 498, 512, and 519 nM, respectively. [Ir(dF(Me)ppy)2(dtbbpy)]PF6 can serve as an electrochemiluminescence-based biological probe.
For research use only. We do not sell to patients.
- CAS No.: 1335047-34-1
- Formula: C42H40F10IrN4P
- Molecular Weight:1013.97
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Storage:
4°C, protect from light, stored under nitrogen
* In solvent : -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen)
Biological Activity
[Ir(dF(Me)ppy)2(dtbbpy)]PF6 (Compound 3a) exhibits ECL activity under annihilation conditions in anhydrous ACN, generating sky-blue to blue-green light[1].
MedChemExpress (MCE) has not independently confirmed the accuracy of these methods. They are for reference only.
Chemical Information
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CAS No. 1335047-34-1
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Appearance Solid
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Molecular Weight 1013.97
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Formula C42H40F10IrN4P
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Color White to yellow
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SMILES
FC1=CC(F)=C(C2=[N]3C=C(C)C=C2)C([Ir+]345([N]6=CC=C(C(C)(C)C)C=C6C7=[N]5C=CC(C(C)(C)C)=C7)C(C=C(F)C=C8F)=C8C9=[N]4C=C(C)C=C9)=C1.F[P-](F)(F)(F)(F)F
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Shipping
Room temperature in continental US; may vary elsewhere.
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Storage
4°C, protect from light, stored under nitrogen
* In solvent : -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen)
Solvent & Solubility
DMSO : 100 mg/mL (98.62 mM; Need ultrasonic; Hygroscopic DMSO has a significant impact on the solubility of product, please use newly opened DMSO)
Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.
Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.
Concentration (start) × Volume (start) = Concentration (final) × Volume (final)
Purity & Documentation
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Data Sheet (279 KB)
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SDS (394 KB)
- English - EN (394 KB)
- Français - FR (394 KB)
- Deutsch - DE (394 KB)
- Norwegian - NO (394 KB)
- Español - ES (394 KB)
- Swedish - SV (394 KB)
- Italian - IT (394 KB)
- Korean - KR (394 KB)
- Portuguese - PT (394 KB)
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Handling Instructions (2659 KB)
References
Complete Stock Solution Preparation Table
Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.
| Optional Solvent | Concentration Solvent Mass | 1 mg | 5 mg | 10 mg | 25 mg |
|---|---|---|---|---|---|
| DMSO | 1 mM | 0.9862 mL | 4.9311 mL | 9.8622 mL | 24.6556 mL |
| 5 mM | 0.1972 mL | 0.9862 mL | 1.9724 mL | 4.9311 mL | |
| 10 mM | 0.0986 mL | 0.4931 mL | 0.9862 mL | 2.4656 mL | |
| 15 mM | 0.0657 mL | 0.3287 mL | 0.6575 mL | 1.6437 mL | |
| 20 mM | 0.0493 mL | 0.2466 mL | 0.4931 mL | 1.2328 mL | |
| 25 mM | 0.0394 mL | 0.1972 mL | 0.3945 mL | 0.9862 mL | |
| 30 mM | 0.0329 mL | 0.1644 mL | 0.3287 mL | 0.8219 mL | |
| 40 mM | 0.0247 mL | 0.1233 mL | 0.2466 mL | 0.6164 mL | |
| 50 mM | 0.0197 mL | 0.0986 mL | 0.1972 mL | 0.4931 mL | |
| 60 mM | 0.0164 mL | 0.0822 mL | 0.1644 mL | 0.4109 mL | |
| 80 mM | 0.0123 mL | 0.0616 mL | 0.1233 mL | 0.3082 mL |
- [Ir(dF(Me)ppy)2(dtbbpy)]PF6
- 1335047-34-1
- Fluorescent Dye
- DFT/TDDFT calculations
- phosphorescence energies
- electrochemiluminescence-based biological probe
- excited-state lifetime
- 2-(2,4-difluorophenyl)-5-methylpyridine
- 4,4'-di-tert-butyl-2,2'-bipyridine
- triplet excited state
- iridium(III) complex
- ECL-active
- charge-transfer state
- Inhibitor
- inhibitor
- inhibit