7000-27-3
Chemical Structure
Methyl β-D-glucopyranoside hemihydrate
Synonym(s): Methyl β-D-glucoside hemihydrate
- CAS No.: 7000-27-3
- Formula:C7H14O6.1/2H2O
- Molecular Weight:203.19
SMILES: O[C@H]([C@H]([C@@H]([C@@H](CO)O1)O)O)[C@@H]1OC.[1/2].O
Biological Activity: Methyl β-D-glucopyranoside (Methyl β-D-glucoside) hemihydrate is a model glycosyl acceptor for enzymatic glycosylation reactions. Methyl β-D-glucopyranoside hemihydrate participates in glycoside synthesis and can react with acyl donors such as caffeic acid esters under the catalysis of specific enzymes (such as Lipozyme TL IM) to achieve acylation modification. Methyl β-D-glucopyranoside hemihydrate can be used in organic synthesis and biocatalysis research, especially the efficient enzymatic preparation of medicinal glycosides (such as Robustaside B (HY-N2720), 6-O-caffeoyl salidroside)[1][2].
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Methyl β-D-glucopyranoside hemihydrate | Methyl β-D-glucopyranoside (Methyl β-D-glucoside) hemihydrate is a model glycosyl acceptor for enzymatic glycosylation reactions. Methyl β-D-glucopyranoside hemihydrate participates in glycoside synthesis and can react with acyl donors such as caffeic acid esters under the catalysis of specific enzymes (such as Lipozyme TL IM) to achieve acylation modification. Methyl β-D-glucopyranoside hemihydrate can be used in organic synthesis and biocatalysis research, especially the efficient enzymatic preparation of medicinal glycosides (such as Robustaside B (HY-N2720), 6-O-caffeoyl salidroside). | |||||||||||||||||||||
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- [1]. Chyba A, et al. Effective enzymatic caffeoylation of natural glucopyranosides. Bioorg Med Chem Lett. 2016;26(6):1567-1570. [Content Brief]
- [2]. Hosoya T, et al. Thermal degradation of methyl beta-D-glucoside. a theoretical study of plausible reaction mechanisms. J Org Chem. 2009;74(17):6891-6894. [Content Brief]
