123148-15-2
Chemical Structure
Ru(dpp)3(PF6)2
- CAS No.: 123148-15-2
- Formula:C72H48F12N6P2Ru
- Molecular Weight:1388.19
InChIKey: GUALHCKQGYAQFA-UHFFFAOYSA-N
SMILES: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[N]12=CC=C(C3=CC=CC=C3)C(C=C4)=C1C5=C4C(C6=CC=CC=C6)=CC=[N]5[Ru+2]278([N]9=CC=C(C%10=CC=CC=C%10)C(C=C%11)=C9C%12=C%11C(C%13=CC=CC=C%13)=CC=[N]8%12)[N]%14=CC=C(C%15=CC=CC=C%15)C(C=C%16)=C%14C%17=C%16C(C%18=CC=CC=C%18)=CC=[N]7%17
Biological Activity: Ru(dpp)3(PF6)2 is a ruthenium (II) polypyridine complex and oxygen-sensing luminophore with excellent photostability and bright orange emission properties based on metal-to-ligand charge transfer (MLCT). Ru(dpp)3(PF6)2 undergoes oxygen-induced collisional luminescence quenching following the Stern-Volmer relationship, and can also engage in Förster-type resonance energy transfer with closed-form BTF6. Featuring excellent photophysical and electrochemical properties, Ru(dpp)3(PF6)2 is applied in studies on quenching-type oxygen sensors based on fluorinated ORMOSIL/xerogels and solid-state light-emitting devices[1][2][3].
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Ru(dpp)3(PF6)2 | 98.20% | Ru(dpp)3(PF6)2 is a ruthenium (II) polypyridine complex and oxygen-sensing luminophore with excellent photostability and bright orange emission properties based on metal-to-ligand charge transfer (MLCT). Ru(dpp)3(PF6)2 undergoes oxygen-induced collisional luminescence quenching following the Stern-Volmer relationship, and can also engage in Förster-type resonance energy transfer with closed-form BTF6. Featuring excellent photophysical and electrochemical properties, Ru(dpp)3(PF6)2 is applied in studies on quenching-type oxygen sensors based on fluorinated ORMOSIL/xerogels and solid-state light-emitting devices. | ||||||||||||||||||||
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References
- [1]. Bukowski RM, et al. High-performance quenchometric oxygen sensors based on fluorinated xerogels doped with [Ru(dpp)3]2+. Anal Chem. 2005;77(8):2670-2672. [Content Brief]
- [2]. Kozlov D V, et al. Photochemically reversible luminescence lifetime switching in metal− organic systems[J]. The Journal of Physical Chemistry A, 2004, 108(48): 10619-10622.
- [3]. Barbante G J, et al. Solid state spectroelectrochemistry of microparticles of ruthenium diimine complexes immobilised on optically transparent electrodes[J]. Journal of Solid State Electrochemistry, 2009, 13(4): 599-608.
