485-64-3
485-64-3
Chemical Structure
Hydrocinchonidine
- CAS No.: 485-64-3
- Formula:C19H24N2O
- Molecular Weight:296.41
IUPAC Name: (R)-((1S,2S,4S,5R)-5-ethylquinuclidin-2-yl)(quinolin-4-yl)methanol
InChIKey: WFJNHVWTKZUUTR-KODHJQJWSA-N
SMILES: O[C@H](C1=CC=NC2=C1C=CC=C2)[C@@]3([H])[N@@](CC4)C[C@H](CC)[C@]4([H])C3
Biological Activity: Hydrocinchonidine is an alkaloid that can be used as a chiral base in the 1,3-dipolar cycloaddition reactions of alkenes and azomethine ylides using silver fluoride. Hydrocinchonidine can also be used to synthesize molecules withoptically active quaternary centers via the aza-Henry reaction[1][2].
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Hydrocinchonidine | Hydrocinchonidine is an alkaloid that can be used as a chiral base in the 1,3-dipolar cycloaddition reactions of alkenes and azomethine ylides using silver fluoride. Hydrocinchonidine can also be used to synthesize molecules withoptically active quaternary centers via the aza-Henry reaction. | |||||||||||||||||||||
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(8α,9R)-10,11-dihydro-Cinchonan-9-ol (Standard) | ≥98% | (8α,9R)-10,11-dihydro-Cinchonan-9-ol (Standard) is the analytical standard of (8α,9R)-10,11-dihydro-Cinchonan-9-ol. This product is intended for research and analytical applications. | ||||||||||||||||||||
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References
- [1]. Alemparte C, et al., A convenient procedure for the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides and alkenes. Org Lett. 2005 Oct 13;7(21):4569-72. [Content Brief]
- [2]. Knudsen KR, et al., A chiral molecular recognition approach to the formation of optically active quaternary centres in aza-Henry reactions. Org Biomol Chem. 2005 Apr 21;3(8):1362-4. [Content Brief]
