873-55-2
873-55-2
Chemical Structure
Sodium benzenesulfinate
- CAS No.: 873-55-2
- Formula:C6H5NaO2S
- Molecular Weight:164.16
IUPAC Name: sodium benzenesulfinate
InChIKey: CHLCPTJLUJHDBO-UHFFFAOYSA-M
SMILES: O=S(C1=CC=CC=C1)O[Na]
Biological Activity: Sodium benzenesulfinate is a reagent used in organic synthesis to create other compounds, such as sulfones. Sodium benzenesulfinate undergoes rhodium-catalyzed desulfinative coupling with aldehydes to yield ketones[1][2].
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Sodium benzenesulfinate | 99.91% | Sodium benzenesulfinate is a reagent used in organic synthesis to create other compounds, such as sulfones. Sodium benzenesulfinate undergoes rhodium-catalyzed desulfinative coupling with aldehydes to yield ketones. | ||||||||||||||||||||
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References
- [1]. Watanabe Si, et al. A novel stereoselective preparation of various vinyl sulfide derivatives using beta-alkylthioalkenylselenonium salts. J Org Chem. 2000 Dec 29;65(26):8893-8. [Content Brief]
- [2]. Rao H, et al. Rhodium‐Catalyzed Aerobic Coupling between Aldehydes and Arenesulfinic Acid Salts: A Novel Synthesis of Aryl Ketones. Advanced Synthesis & Catalysis. 2011 Jul;353(10):1701-6.
