139979-81-0
Chemical Structure
Angulatin A
Synonym(s): (-)-Angulatin A; Celangulin V
- CAS No.: 139979-81-0
- Formula:C34H46O13
- Molecular Weight:662.72
IUPAC Name: (3S,4S,5S,5aS,6R,7S,9S,9aS,10R)-5-(benzoyloxy)-9,10-dihydroxy-4-(isobutyryloxy)-5a-((isobutyryloxy)methyl)-2,2,9-trimethyloctahydro-2H-3,9a-methanobenzo[b]oxepine-6,7-diyl diacetate
InChIKey: HAHJPPZGVANYSD-PNVCEFGPSA-N
SMILES: CC(C)C(OC[C@]12[C@H](OC(C3=CC=CC=C3)=O)[C@@H](OC(C(C)C)=O)[C@@]([C@H]4O)([H])C(C)(C)O[C@@]14[C@@](C)(O)C[C@H](OC(C)=O)[C@@H]2OC(C)=O)=O
Biological Activity: Angulatin A (Celangulin V) is a natural product that can be found in Celastrus angulatus[1]. Angulatin A is a novel botanical insecticide with a toxic activity against agricultural insect pests. Angulatin A can bind to subunits a, H, and B of the vacuolar ATPase (V-ATPase) in the midgut epithelial cells of insects[2].
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Angulatin A | Angulatin A (Celangulin V) is a natural product that can be found in Celastrus angulatus. Angulatin A is a novel botanical insecticide with a toxic activity against agricultural insect pests. Angulatin A can bind to subunits a, H, and B of the vacuolar ATPase (V-ATPase) in the midgut epithelial cells of insects. | |||||||||||||||||||||
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References
- [1]. Hai-Yan Zhang, et al. Four new sesquiterpene polyol esters from Celastrus angulatus, Phytochemistry Letters. 2014,7, 101-106.
- [2]. Ding L, Guo Z, Xu H, Li T, Wang Y, Tao H. The Inhibitory Effect of Celangulin V on the ATP Hydrolytic Activity of the Complex of V-ATPase Subunits A and B in the Midgut of Mythimna separata. Toxins (Basel). 2019 Feb 22;11(2):130.
