γ-Terpinene synthase

γ-Terpinene synthase (EC 4.2.3.114) requires Mg2+. Mn2+ less effective. The reaction involves a 1,2-hydride shift. The 5-pro-S hydrogen of geranyl diphosphate is lost. Traces of several other monoterpenoids are formed in addition to γ-Terpinene.

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