Visible-Light-Promoted Synthesis of Dibenzofuran Derivatives

  • J Org Chem. 2018 Jan 19;83(2):805-811. doi: 10.1021/acs.joc.7b02796.
Ji Young Cho  1 Geum-Bee Roh  1 Eun Jin Cho  1
Affiliations
  • 1. Department of Chemistry, Chung-Ang University , 84 Heukseok-ro, Dongjak-gu, Seoul 06974, Republic of Korea.
Abstract

Dibenzofurans are naturally occurring molecules that have received considerable attention for a variety of practical applications, such as in pharmaceuticals and electronic Materials. Herein, an efficient and eco-friendly method for the synthesis of dibenzofuran derivatives via intramolecular C-O bond formation, which involves the in situ production of a diazonium salt, is described. The transformation requires a diazotizing agent and is promoted by the use of an organic Photosensitizer under visible-light irradiation.

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