Structural revisions of some non-adjacent bis-tetrahydrofuran annonaceous acetogenins

  • J Nat Prod. 1993 Jul;56(7):1095-100. doi: 10.1021/np50097a013.
X P Fang  1 ,  Z M Gu ,  M J Rieser ,  Y H Hui ,  J L McLaughlin ,  M Nonfon ,  F Lieb ,  H F Moeschler ,  D Wendisch
Affiliations
  • 1. Department of Medicinal Chemistry and Pharmacognosy, School of Pharmacy and Pharmacal Sciences, Purdue University, West Lafayette, Indiana 47907.
PMID: 8377016 DOI: 10.1021/np50097a013
Abstract

The relative stereochemistries of bullatalicin [1] and bullatalicinone [2] were partially reassigned based on COSY and relayed COSY spectra. The structures of annonins VIII [3], IV [4], and XVI [5] were revised and concluded as bullatalicin [1], bullatanocin [6], and squamostatin A [7], respectively.