TPO-L
Based on 1 Customer Validation
TPO-L is a photoinitiator for the 3D printing of resin that promotes two-photon induced polymerization. The two-photon absorption cross-section spectrum of Lucirin TPO-L shows a maximum of 1.2 GM at 610 nm. Despite its small two-photon absorption cross-section, Lucirin TPO-L exhibits high polymerization quantum yields.
For research use only. We do not sell to patients.
- Purity: 99.77%
- CAS No.: 84434-11-7
- Formula: C18H21O3P
- Molecular Weight:316.33
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Storage:
4°C, protect from light
* In solvent : -80°C, 6 months; -20°C, 1 month (protect from light)
Biological Activity
Preparation for TPO-L solution:[1]
Lucirin TPO-L/ethanol solution with concentrations of 7×10−3 and 9×10−1 M.
TPO-L fpr 3D Printing of Resin:[2]
For printing, 50 g of Cubiflow with 1.18 wt % TPO-L as photoinitiator and 0.05 wt % UV-1995 as UV-Vis absorber were prepared. Curing was done with an intensity of 4 mW cm−2 and 40 s exposure per layer. The layer height was set to 50 µm. The specimens were oriented flat on the XY-plane and printed without support structures. One set was post-cured for 300 s in the UV flood curing system, and the other set was used as printed (green).
MedChemExpress (MCE) has not independently confirmed the accuracy of these methods. They are for reference only.
Chemical Information
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CAS No. 84434-11-7
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Appearance Liquid (Density: 1.14±0.1 g/cm3)
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Molecular Weight 316.33
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Formula C18H21O3P
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Color Light yellow to brown
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SMILES
O=C(P(OCC)(C1=CC=CC=C1)=O)C2=C(C)C=C(C)C=C2C
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Shipping
Room temperature in continental US; may vary elsewhere.
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Storage
4°C, protect from light
* In solvent : -80°C, 6 months; -20°C, 1 month (protect from light)
Solvent & Solubility
DMSO : ≥ 175 mg/mL (553.22 mM; Hygroscopic DMSO has a significant impact on the solubility of product, please use newly opened DMSO)
* "≥" means soluble, but saturation unknown.
Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (protect from light). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.
Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (protect from light). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.
Concentration (start) × Volume (start) = Concentration (final) × Volume (final)
Purity & Documentation
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Data Sheet (275 KB)
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SDS (537 KB)
- English - EN (537 KB)
- Français - FR (537 KB)
- Deutsch - DE (537 KB)
- Norwegian - NO (537 KB)
- Español - ES (537 KB)
- Swedish - SV (537 KB)
- Italian - IT (537 KB)
- Korean - KR (537 KB)
- Portuguese - PT (537 KB)
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Handling Instructions (2659 KB)
References
[2]. Steyrer B, et al. Visible Light Photoinitiator for 3D-Printing of Tough Methacrylate Resins. Materials (Basel). 2017 Dec 19;10(12):1445. [Content Brief]
[3]. Kim GT, et al. Cytotoxicity, Colour Stability and Dimensional Accuracy of 3D Printing Resin with Three Different Photoinitiators. Polymers (Basel). 2022 Feb 28;14(5):979. [Content Brief]
Complete Stock Solution Preparation Table
Please refer to the solubility information to select the appropriate solvent. Once prepared, please aliquot and store the solution to prevent product inactivation from repeated freeze-thaw cycles.
Storage method and period of stock solution: -80°C, 6 months; -20°C, 1 month (protect from light). When stored at -80°C, please use it within 6 months. When stored at -20°C, please use it within 1 month.
| Optional Solvent | Concentration Solvent Mass | 1 mg | 5 mg | 10 mg | 25 mg |
|---|---|---|---|---|---|
| DMSO | 1 mM | 3.1613 mL | 15.8063 mL | 31.6126 mL | 79.0314 mL |
| 5 mM | 0.6323 mL | 3.1613 mL | 6.3225 mL | 15.8063 mL | |
| 10 mM | 0.3161 mL | 1.5806 mL | 3.1613 mL | 7.9031 mL | |
| 15 mM | 0.2108 mL | 1.0538 mL | 2.1075 mL | 5.2688 mL | |
| 20 mM | 0.1581 mL | 0.7903 mL | 1.5806 mL | 3.9516 mL | |
| 25 mM | 0.1265 mL | 0.6323 mL | 1.2645 mL | 3.1613 mL | |
| 30 mM | 0.1054 mL | 0.5269 mL | 1.0538 mL | 2.6344 mL | |
| 40 mM | 0.0790 mL | 0.3952 mL | 0.7903 mL | 1.9758 mL | |
| 50 mM | 0.0632 mL | 0.3161 mL | 0.6323 mL | 1.5806 mL | |
| 60 mM | 0.0527 mL | 0.2634 mL | 0.5269 mL | 1.3172 mL | |
| 80 mM | 0.0395 mL | 0.1976 mL | 0.3952 mL | 0.9879 mL | |
| 100 mM | 0.0316 mL | 0.1581 mL | 0.3161 mL | 0.7903 mL |